Email this article ANALISIS KANDUNGAN LOGAM Cd, Cu, Cr DAN Pb DALAM AIR LAUT DI SEKITAR PERAIRAN BUNGUS TELUK KABUNG KOTA PADANG
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DOI: https://doi.org/10.25077/dampak.9.2.116-122.2012
Copyright (c) 2012 Bustanul Arifin
Abstract
ABSTRAK
Penelitian mengenai analisis kandungan logam Cd, Cu, Cr dan Pb dalam air laut telah dilakukan di sekitar perairan Bungus, Teluk Kabung, Kota Padang dengan menggunakan metode ekstraksi pelarut. Hasil penelitian ini bertujuan untuk mengetahui kandungan logam, Cu, Cr dan Pb dan sebarannya di perairan Bungus. Sampel sebanyak 200 mL diekstraksi dengan larutan pengompleks ammonium pyrolidin ditiokarbamat (APDC) jenuh sebanyak 2 mL dalam 7 mL metil isobutyl keton (MIBK) dan diekstrak kembali dengan 5 mL larutan HNO3 4M, larutan diukur absorbannya dengan Spektrofotometer Serapan Atom (SSA). Pengambilan sampel air laut dilakukan sebanyak 6 lokasi yaitu di sekitar Pelabuhan Perikanan Samudera, pantai Carolin, Depot Pertamina, Teluk Pandan, UPTD BBIP (Balai Benih Ikan Pantai) Teluk Buo dan di laut lepas, dimana tiap lokasi diambil 2 titik sampel dengan jarak antar titik sekitar 100 m dengan dua kali pengambilan. Dari hasil penelitian didapatkan bahwa kandungan logam Cd berkisar antara 0,006 0,01 ppm, Cu antara 0,0058 0,0720 ppm, Cr antara 0,0170 - 0,0890 ppm dan kandungan logam Pb berkisar antara 0,06 0,09 ppm. Menurut Keputusan Menteri Negara Lingkungan Hidup No. 51 Tahun 2004 kandungan logam Cr dan Pb telah melampaui standar baku mutu air laut yaitu 0,001 ppm sedangkan kandungan logam Cd dan Cu belum melampaui standar baku mutu air laut.
Kata Kunci : ekstraksi pelarut, APDC, MIBK dan SSA
ABSTRACT
Research on metal concentrations of Cd, Cu, Cr and Pb was analyzed in sea water around Bungus, Teluk Kabung, Padang City by utilizing solvent extraction method. The research was conducted to see metal contents and their distribution in Bungus. Sample of 200 ml was extracted with 2 ml solution of saturated ammonium pyrolidine dithiocarbamate (APCD) in 7 ml methyl isobutyl ketone (IBK) and being extracted again with 5 ml HNO3 4M. Solution was measured its absorbance by using Atomic Absorbtion Spectroscopy (AAS). Sea water samples was taken in six locations; around Samudera Fishery Port, Carolin Beach, gas station, Pandan Bay, UPTD BBIP Buo Bay and in the sea, 2 sampling points were set with 100 m distance between each point. Results show the range of Cd concentration was 0.006-0.01 ppm, Cu was 0.0058-0.0720 ppm, Cr was 0.0170-0.0890 ppm and Pb was 0.06-0.09 ppm. Compared with the regulation of Environment Ministry number 51 Year 2004, concentrations of Cr and Pb exceeded the quality standard of sea water of 0.001 ppm. On the other hand, Cd and Cu concentrations were found below the sea water quality standard.
Keywords: AAS, APCD, MIBK, solvent exraction
Penelitian mengenai analisis kandungan logam Cd, Cu, Cr dan Pb dalam air laut telah dilakukan di sekitar perairan Bungus, Teluk Kabung, Kota Padang dengan menggunakan metode ekstraksi pelarut. Hasil penelitian ini bertujuan untuk mengetahui kandungan logam, Cu, Cr dan Pb dan sebarannya di perairan Bungus. Sampel sebanyak 200 mL diekstraksi dengan larutan pengompleks ammonium pyrolidin ditiokarbamat (APDC) jenuh sebanyak 2 mL dalam 7 mL metil isobutyl keton (MIBK) dan diekstrak kembali dengan 5 mL larutan HNO3 4M, larutan diukur absorbannya dengan Spektrofotometer Serapan Atom (SSA). Pengambilan sampel air laut dilakukan sebanyak 6 lokasi yaitu di sekitar Pelabuhan Perikanan Samudera, pantai Carolin, Depot Pertamina, Teluk Pandan, UPTD BBIP (Balai Benih Ikan Pantai) Teluk Buo dan di laut lepas, dimana tiap lokasi diambil 2 titik sampel dengan jarak antar titik sekitar 100 m dengan dua kali pengambilan. Dari hasil penelitian didapatkan bahwa kandungan logam Cd berkisar antara 0,006 0,01 ppm, Cu antara 0,0058 0,0720 ppm, Cr antara 0,0170 - 0,0890 ppm dan kandungan logam Pb berkisar antara 0,06 0,09 ppm. Menurut Keputusan Menteri Negara Lingkungan Hidup No. 51 Tahun 2004 kandungan logam Cr dan Pb telah melampaui standar baku mutu air laut yaitu 0,001 ppm sedangkan kandungan logam Cd dan Cu belum melampaui standar baku mutu air laut.
Kata Kunci : ekstraksi pelarut, APDC, MIBK dan SSA
ABSTRACT
Research on metal concentrations of Cd, Cu, Cr and Pb was analyzed in sea water around Bungus, Teluk Kabung, Padang City by utilizing solvent extraction method. The research was conducted to see metal contents and their distribution in Bungus. Sample of 200 ml was extracted with 2 ml solution of saturated ammonium pyrolidine dithiocarbamate (APCD) in 7 ml methyl isobutyl ketone (IBK) and being extracted again with 5 ml HNO3 4M. Solution was measured its absorbance by using Atomic Absorbtion Spectroscopy (AAS). Sea water samples was taken in six locations; around Samudera Fishery Port, Carolin Beach, gas station, Pandan Bay, UPTD BBIP Buo Bay and in the sea, 2 sampling points were set with 100 m distance between each point. Results show the range of Cd concentration was 0.006-0.01 ppm, Cu was 0.0058-0.0720 ppm, Cr was 0.0170-0.0890 ppm and Pb was 0.06-0.09 ppm. Compared with the regulation of Environment Ministry number 51 Year 2004, concentrations of Cr and Pb exceeded the quality standard of sea water of 0.001 ppm. On the other hand, Cd and Cu concentrations were found below the sea water quality standard.
Keywords: AAS, APCD, MIBK, solvent exraction
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